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№ 36 · CHEMISTRY

Sparkling Water, Lemon, and Enamel Erosion: How Dangerous Are Acidic Drinks

2026年6月12日 · QDRO

Dentists are seeing more enamel erosion — and increasingly, the cause isn't cola. It's lemon water carried in a thermos all day, fruit smoothies, sports isotonics. The problem isn't that people drink harmful things. The problem is that people don't know which things actually harm.

Erosion is not caries and not abrasion

Three mechanisms damage teeth differently.

Caries is bacteria. Streptococci ferment sugar, release acid locally under plaque. Damage is localised, often on proximal surfaces.

Abrasion is mechanical. A too-hard brush, wrong technique, hard particles in the paste. Wear happens where there's pressure.

Erosion is chemical dissolution by externally applied acid. No bacteria. No friction. Just contact between an acidic solution and the hydroxyapatite of enamel. A proton strips calcium and phosphate — enamel literally goes into solution. The pattern is diffuse: smoothed incisal edges, cupping on occlusal surfaces, thinning of anterior teeth.

The critical threshold is pH 5.5. Below this value, hydroxyapatite begins to dissolve.

pH matters — but it's not the full picture

The first instinct is to look at pH. The logic is correct but incomplete.

Coca-Cola: pH around 2.4. Lemon juice: pH 2.2–2.5. Orange juice: pH 3.5–4.0. Sports drinks like Gatorade: pH 2.9–3.4. Plain carbonated water without flavourings: pH 5.0–5.5.

Here's the paradox: diet cola at pH 2.5 sometimes causes less erosion than orange juice at pH 3.8. Because pH is only the "initial acidity." Equally important is titratable acidity — how much total acid must be neutralised to bring pH above a safe level.

Carbonic acid in sparkling water (the product of dissolved CO₂) is weak and has low buffering capacity. Saliva neutralises it in minutes. Citric acid is different. It doesn't just lower pH — it chelates calcium: it binds calcium ions into complexes, disrupting the mineral equilibrium at the enamel surface.

pH ~5.1plain sparkling water without additives (carbonic acid)ADA Science Center, 2022
pH ~2.5lemon water / lemonade (citric acid)PMID 11580825

A 2001 study (PMID 11580825, Lussi et al.) showed that at equal pH, citric acid dissolves hydroxyapatite more aggressively than other acids. The mechanism is the combination of low pH and high titratable acidity.

Sparkling water is not cola

This is one of the most persistent myths in dental practice. Plain carbonated water gets equated with soda — even though they are chemically incomparable.

A 2007 study (PMID 17263857, Parry et al., International Journal of Paediatric Dentistry) compared the erosive potential of different water types. The result was clear: plain sparkling water without flavour additives produced virtually no more erosion than still water. Neither caused significant enamel damage.

But flavoured sparkling waters — lemon, citrus, berry — showed pH of 2.74–3.34 and high titratable acidity (0.34–0.66 mmol). Their erosive potential was comparable to or exceeded that of orange juice.

Drinking plain sparkling water and worrying about enamel erosion: no basis for concern. Drinking lemon-flavoured sparkling water as a daily substitute for plain water: worth reconsidering.

Why "healthy" drinks are more dangerous than cola

The paradox of modern nutrition: cola is seen as bad (and avoided), while lemon water in a thermos is seen as healthy. This changes behaviour.

People drink lemon water slowly and continuously — throughout the entire day. The acid attack lasts for hours. It's the duration and frequency of contact that determines real damage, not just the pH value.

Fruit smoothies: pH 3.5–4.0, high citric and malic acid content. Kombucha: pH 2.5–3.5 with organic acids. Sports isotonics: pH 2.9–3.4, citric acid used as an acidity regulator. Energy drinks: pH 2.4–3.4, comparable in aggressiveness to cola.

It doesn't matter whether a drink is "healthy" or not. What matters is its pH, how much acid it contains, and how long it stays in contact with teeth.

A study (PMC5588266, Venkatesh Babu, 2017) demonstrated significant enamel volume loss after in vitro exposure to energy and sports drinks. Changes were measurable even at brief exposure durations.

What actually reduces the risk

Research provides several working recommendations — with varying levels of evidence.

Drink quickly and through a straw. The less time an acidic drink contacts teeth, the less damage. A straw positioned toward the back of the mouth reduces contact with anterior teeth (PMID 9785633). Not a cure, but a reduction in exposure.

Don't rinse immediately after. The intuitive gesture — rinse with water after an acidic drink. Data: this helps marginally but produces no significant protective effect. Better to simply not sip slowly over an extended period.

Don't brush immediately. After acid contact, enamel surface is softened — hydroxyapatite crystals are partially demineralised. A toothbrush at this moment mechanically removes the weakened layer. The standard recommendation: wait 30–60 minutes. Saliva neutralises the acid and initiates remineralisation during that window.

Fluoride and hydroxyapatite. Fluorapatite, formed with regular fluoride use, is less soluble in acid than native hydroxyapatite. Not a protective barrier, but reduced vulnerability. Nano-hydroxyapatite works differently — it integrates into micro-defects in enamel and restores structure (PMC9609919).

Dairy and cheese. Calcium and phosphate from dairy products elevate the concentration of these ions in saliva and dental plaque. Cheese after an acidic drink is a practical strategy. Several studies showed that CPP-ACP (casein phosphopeptide-amorphous calcium phosphate) reduces the erosiveness of acidic drinks when added to them (PMID 20887514).

What this means in practice

Enamel erosion is not a hypothetical risk. It happens with regular consumption of acidic drinks — especially when people sip them slowly and frequently.

Practical hierarchy by aggressiveness: lemon water and lemonade at the top. Orange juice, smoothies, kombucha at the next level. Sports and energy drinks comparable. Cola aggressive, but due to low titratable acidity (phosphoric, not citric) sometimes slightly less destructive than it appears. Plain sparkling water: essentially safe.

You don't need to change everything. You need to change two behaviours: stop prolonging contact with acidic drinks, and let saliva do its job after. Enamel doesn't regenerate — but saliva protects it, if you don't get in the way.

30 minminimum wait before brushing after acid exposurePMID 10529531, in situ study
pH 5.5critical dissolution threshold for hydroxyapatiteLussi, Dental Erosion, 2006

Sources: Lussi et al., 2001 (PMID 11580825) · Parry et al., 2007 (PMID 17263857) · Moazzez & Bartlett, systematic review 2020 (PMID 33052542) · Attin et al., in situ 1999 (PMID 10529531) · Devji et al., 2020 (PMID 20887514) · Venkatesh Babu, 2017 (PMC5588266) · Erosive tooth wear risk groups, 2024 (PMID 39387908) · ADA MouthHealthy: Sparkling Water and Teeth